๐ Revolutionizing Magnesium Batteries: A Cost-Effective Boron-Based Electrolyte with Smart Interface Engineering
⚡ The Challenge:
Rechargeable magnesium batteries (RMBs) are strong contenders in the race for next-gen energy storage thanks to magnesium’s high abundance ๐, enhanced safety ๐ก️, and impressive volumetric capacity ๐ฆ. But there's a catch — creating boron-based electrolytes that are both efficient and scalable has been a long-standing bottleneck ๐งช๐ธ.๐ง The Innovation:
A new magnesium phenyl fluoroborate complex (MPFBC) electrolyte offers a practical solution. Designed using cheap and accessible boron trifluoride ๐ฐ, MPFBC is synthesized through a simple Lewis acid-base reaction ⚗️, avoiding the need for complex or costly procedures.๐ง Performance That Delivers:
This novel electrolyte enables:-
Stable cycling of Mg||Mg symmetric cells at 0.5 mA cm⁻² ๐
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Low overpotential of <100 mV ⚡
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Long-term cycling with 62.6 mAh g⁻¹ specific capacity after 1000 cycles in Mg||Mo₆S₈ cells ๐๐
๐งฌ Interface Engineering, Redefined:
What truly sets this work apart is its dual-mode interface regulation:-
Chemical process: In-situ pre-corrosion ๐งช
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Electrochemical process: Formation of a Mg²⁺-conductive layer ๐
Together, these strategies harmonize interface chemistry ๐ค, making the Mg anode more stable and robust over time. This marks the first reported complementation of chemistry and electrochemistry to actively control the interface behavior in RMBs ๐.
๐ Why This Matters:
This development not only cuts down on costs ๐ธ and complexity ๐งฉ, but also introduces a scalable path to commercialization ๐ for boron-based electrolytes. It also enriches our scientific understanding of interface dynamics ๐ง ๐ฌ in multivalent batteries.✅ The Takeaway:
With MPFBC and its novel interface strategy, we're a step closer to safe, affordable, and durable energy storage solutions ๐ฑ๐. It’s not just a material breakthrough — it’s a paradigm shift in how we approach electrolyte design and interface chemistry.
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